Dr. Hemanta Kumar Kisan

 
Dr. Hemanta Kumar Kisan
Assistant Professor
Ph.D, IIT Bombay
hemant[*AT]iitp.ac.in
ORCID: https://orcid.org/0000-0003-1542-9021
Research Areas : Computational Organic Chemistry, Asymmetric Catalysis, Transition metal Catalysis, Enzyme Catalysis, Catalyst Design
Awards & Honours :
  • Institute Excellence in PhD Thesis Award 2017.” Indian Institute of Technology Bombay, Mumbai, India
  • Qualified CSIR-JRF-NET 2010
Sponsored projects :
TitlePrincipal InvestigaterSponsored byStatus
Transition State Modeling on Cooperative Multi-Catalytic Asymmetric Reactions Dr. Hemanta Kumar Kisan (P.I) Government of Odisha Science and Technology Department Ongoing
Understanding P450 Enzyme Catalysis and harnessing the Origin of Selectivity for Enzyme/Biomimetic Catalyst Design using DFT and QM/MM Computation Dr. Hemanta Kumar Kisan (P.I) Utkal University, Odisha under WB-OHEPEE Programme Ongoing
No. of Ph.D Students :
  • Prafulla Kumar Behera (Utkal University, Odisha)
Professional Experience :
  • Assistant Professor (Department of Chemistry, IIT Patna, Bihar 3rd January 2023- continuing)
  • Assistant Professor (Department of Chemistry, Utkal University, Odisha, 17th December 2014-2nd January 2023).
  • Postdoctoral Research Fellow (The Hebrew University of Jerusalem, Israel, 18th August 2019-26th August 2020).
Publications :
  1. Mondal, A.; Sahu, P.; Kisan, H. K.; Isab, A. A. Chandra, S. K. ; Dinda, J. “Dinuclear silver(I)- and gold(I)- N heterocyclic carbene complexes; synthesis, structural characterizations, Photoluminescence and theoretical studies.” J. Mol. Struct. 2022, DOI: 10.1016/j.molstruc.2022.134430.
  2. Jena, S.; Tulsiyan, K. D.; Kar, R. K.; Kisan, H. K.; Biswal H. S. “Doubling Förster Resonance Energy Transfer Efficiency in Proteins with Extrinsic 2-Thioamide Probes: Implications to Thio-modified Nucleobases.’’ Chem. Eur. J. 2021, 27, 4373.
  3. Kumar, A.; Kisan, H. K.; Huynh, H. V. “Reactivity Studies and Electronic Properties of an N-Arylated Acyclic Amino Carbene” Organometallics 2021, 40, 1699.
  4. Pradhan, K. C.; Kisan, H. K.; Pal, S. “Unexpected ortho C-H bond activation in coordinated 7,8-benzoquinoline: Synthesis and characterisation of heteroleptic Ir(III)-7,8-benzoquinoline complexes.” RSC Adv. 2021, 11, 12578.
  5. Purohit, A. K.; Kisan, H. K.; Sahu, S.; Kar, P. K. “Highly selective and sensitive optical discrimination of Pyrophosphate ion by a Zn(ll)-terpyridine complex in aqueous medium at physiological pH.” J. Mol. Struct. 2021, 1243, 130868.
  6. Behera, P. K.; Kisan, H. K.; Isab, A. A.; Dinda, J. “Novel synthesis, structural characterization, DFT and TDDFT investigation of ‘Butterfly’ like Ag(I)- complex supported by 3-pyrazinyl[1-methyl)imidazolium hexaflurophosphate.” J. Mol. Struct. 2021, 1235, 130188.
  7. Behera, P. K.; Maity, L.; Kisan, H. K.; Dutta, B.; Isab, A. A.; Chandra, S. K.; Dinda, J. “Gold(I) and Gold(III) Complexes Supported by a pyrazine / pyrimidine wingtip N-Heterocyclic Carbene; Synthesis, Structure and DFT Studies.” J. Mol. Struct. 2021, 1223, 129253.
  8. Kalita, S.; Shaik, S.; Kisan, H. K.; Dubey, K. D. “A Paradigm Shift in the Catalytic Cycle of P450–The Preparatory Choreography During O2 Binding, and Origins of the Necessity for Two Protonation Pathways” ACS Catal., 2020, 10, 11481.
  9. Pradhan, K. C.; Barik, S.; Singh, B. C.; Mohapatra, P.; Kisan, H. K.; Pal, S. “Synthesis, characterisation and theoretical studies of a series of Iridium (III) complexes with Schiff base ligands.” J. Mol. Struct. 2020, 1211, 128058.
  10. Jhulki, L.; Purakait, R.; Kisan, H. K.; Bertolasi, V.; Isab, A. A.; Sinha, C.; Dinda, J. “A promising class of luminescent derivatives of Silver(I) and Gold(I)-N-heterocyclic carbene.” Appl. Organometal. Chem. 2020, 34, e5673. DOI: 10.1002/aoc.5673.
  11. Adhikary, S. D.; Mondal, A.; Kisan, H. K.; Bielawski, C. W.; Dinda, J. “Bipyridyl / Carbazolate-Silver(I) and Gold(I)-N-Heterocyclic Carbene Complexes: A Systematic Study of Geometric Constraints and Electronic Properties.” Appl. Organometal. Chem. 2020, 34 e5335 DOI:10.1002/aoc.5335.
  12. Mondal, A.; Tripathhy, R. K.; Dutta, P.; Santra, M. K.; Isab, A. A.; Bielawski, C. W.; Kisan, H. K.; Chandra, S. K.; Dinda, J. “Ru(II)-based antineoplastic: A “wingtip” N-heterocyclic carbene facilitates access to a new class of organometallics that are cytotoxic to common cancer cell lines.” Appl. Organometal. Chem. 2019, 33, e4692.
  13. Pareek, S.; Jain, D.; Hussain, S.; Biswas, A.; Shrivastava, R.; Parida, S. K.; Kisan, H. K.; Lgaz, H.; Chung, I.-M.; Behera, D. “A New Insight into Corrosion Inhibition Mechanism of Copper in Aerated 3.5 % (by weight) NaCl Solution by Eco-friendly Imidazopyrimidine Dye: Experimental and Theoretical Approach.” Chemical Engineering Journal 2019, 358, 725.
  14. Dinda, J.; Jhulki, L.; Kisan, H. K.; Mahapatra, P. K.; Isab, A. A.; Bielawski, C. W. “Synthesis and Study of Palladium(II) and Platinum(II) Complexes Supported by a Common “Wingtip” N-Heterocyclic Carbene.” ChemistrySelect 2018, 3, 10732.
  15. Kisan, H. K.; Sunoj, R. B. “Insights on the Origin of Regiodivergence in the Parallel Kinetic Resolution of rac-Aziridines using a Chiral Lanthanum-Yttrium Bimetallic Catalyst.” ACS Catal., 2018, 8, 7633.
  16. Maity, L.; Adhikary, S. D.; Mondal, A.; Kisan, H. K.; Isab, A. A.; Goswami, S.; Dinda, J. “Synthesis, Structure, Theoretical Studies and Electrochemistry of Ru(II)-N Heterocyclic Carbenes.”  Inorganica Chimica Acta 2018, 479, 141.
  17. Kisan, H. K.; Sunoj, R. B. “Asymmetric Cooperative Catalysis in a Three-Component Reaction: Mechanism and Origin of Enantio- and Diastereoselectivities” Org. Lett. 2016, 18, 3746.
  18. Kisan, H. K.; Sunoj, R. B. “Axial Coordination Dichotomy in Dirhodium Carbenoid Catalysis: A Curious Case of Cooperative Asymmetric Dual-Catalytic Approach toward Amino Ester.” J. Org. Chem. 2015, 80, 2192.
  19. Jindal, G.; Kisan, H. K.; Sunoj, R. B. “Mechanistic Insights on Cooperative Catalysis through Computational Quantum Chemical Methods.” ACS Catal., 2015, 5, 480.
  20. Kisan, H. K.; Sunoj, R. B. “Deciphering the Origin of Cooperative Catalysis by Dirhodium Acetate and Chiral Spiro Phosphoric Acid in an Asymmetric Amination Reaction.” Chem. Commun, 2014, 50, 14639.
  21. Kolay, S.; Wadawale, A.; Das, D.; Kisan, H. K.; Sunoj, R. B.; Jain, V. K. “Cyclopalladation of dimesityl selenide:synthesis, reactivity, structural characterization, isolation os an intermediate complex with C-H…Pd intra-molecular interaction and computational studies.” Dalton Trans. 2013, 42, 10828.
Follow Us :

Copyright © IITP. All rights reserved.

Total Visits: 
1869820